ASTM D7184 Standard Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure Chemiluminescence
ASTM D7184用氧化燃烧和减压化学发光法测定芳烃中超低氮的试验方法
This test method is useful to detect and quantify nitrogen-containing compounds at a concentration of 0.03 to 1 mg N/kg in light aromatic hydrocarbons used or produced in manufacturing process. These nitrogen-containing compounds are undesirable in finished aromatic products and may be used in setting specification for determining the total nitrogen content in aromatic hydrocarbons.
This test method requires the use of reduced pressure at the detector. Loss of vacuum or pressure fluctuations impact the sensitivity of the detector and the ability to determine nitrogen concentrations less than 1 mg N/kg.
1. Scope
1.1 This test method covers the determination of total nitrogen in aromatic hydrocarbons, such as benzene, toluene, and xylene.
1.2 This test method is applicable for samples containing nitrogen from 0.03 to 1 mg N/kg. For higher nitrogen concentrations refer to Test Method D 6069 or D 4629.
1.3 In determining the conformance of the test results using this method to applicable specifications; results shall be rounded off in accordance with the rounding-off method of Practice E 29.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.
2. Referenced Documents (purchase separately)
ASTM Standards
D3437 Practice for Sampling and Handling Liquid Cyclic Products
D4629 Test Method for Trace Nitrogen in Liquid Petroleum Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection
D6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure Chemiluminescence Detection
D6809 Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
D4629 Test Method for Trace Nitrogen in Liquid Petroleum Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection
D6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure Chemiluminescence Detection
D6809 Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
Other Documents
OSHARegulations,29CF paragraphs 1910. 1000 and 1910.1200
Index Terms
chemiluminescence; nitrogen; reduced pressure;