ASTM D3612 Standard Test Method for Analysis of Gases Dissolved in Electrical Insulating Oil by Gas Chromatography
ASTM D3612用气体色谱分离法分析电绝缘油中溶解的气体成分的标准试验方法
Oil and oil-immersed electrical insulation materials may decompose under the influence of thermal and electrical stresses, and in doing so, generate gaseous decomposition products of varying composition which dissolve in the oil. The nature and amount of the individual component gases that may be recovered and analyzed may be indicative of the type and degree of the abnormality responsible for the gas generation. The rate of gas generation and changes in concentration of specific gases over time are also used to evaluate the condition of the electric apparatus.
Note 1—Guidelines for the interpretation of gas-in-oil data are given in IEEE C57.104.
1. Scope
1.1 This test method covers three procedures for extraction and measurement of gases dissolved in electrical insulating oil having a viscosity of 20 cSt (100 SUS) or less at 40°C (104°F), and the identification and determination of the individual component gases extracted. Other methods have been used to perform this analysis.
1.2 The individual component gases that may be identified and determined include:
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Hydrogen—H2
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Oxygen—O2
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Nitrogen—N2
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Carbon monoxide—CO
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Carbon dioxide—CO2
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Methane—CH4
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Ethane—C2H6
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Ethylene—C2H4
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Acetylene—C2H2
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Propane—C3H8
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Propylene—C3H6
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1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements see 6.1.8, 30.2.2 and 30.3.1.
2. Referenced Documents (purchase separately)
ASTM Standards
D2140 Practice for Calculating Carbon-Type Composition of Insulating Oils of Petroleum Origin
D2300 Test Method for Gassing of Electrical Insulating Liquids Under Electrical Stress and Ionization (Modified Pirelli Method)
D2779 Test Method for Estimation of Solubility of Gases in Petroleum Liquids
D2780 Test Method for Solubility of Fixed Gases in Liquids
D3613 Practice for Sampling Insulating Liquids for Gas Analysis and Determination of Water Content
D4051 Practice for Preparation of Low-Pressure Gas Blends
E260 Practice for Packed Column Gas Chromatography
D2300 Test Method for Gassing of Electrical Insulating Liquids Under Electrical Stress and Ionization (Modified Pirelli Method)
D2779 Test Method for Estimation of Solubility of Gases in Petroleum Liquids
D2780 Test Method for Solubility of Fixed Gases in Liquids
D3613 Practice for Sampling Insulating Liquids for Gas Analysis and Determination of Water Content
D4051 Practice for Preparation of Low-Pressure Gas Blends
E260 Practice for Packed Column Gas Chromatography
IEEE Standard
C57.104 Guide for the Interpretation of Gases Generated in Oil-Immersed Transformers
IEC Standard
PublicationNo.567 Guide for the Sampling of Gases and of Oil from Oil-Filled Electrical Equipment and for the Analysis of Free and Dissolved Gases
Index Terms
capillary columns; combustible gases; dissolved gases; gases; headspace; insulating oil; oil; transformer oil; Dissolved gases; Electrical insulating oils; Gas chromatography (GC)--insulating materials/applications; Gas content;